ごご午後gogo
1.

The period of time that begins after noon and extends to midnight, often associated with post-lunch activities.

2.

Specifically refers to the time frame from midday until evening, marked by a transition from daylight to dusk.

Example:

その急行は午後六時三十分着だ。

ごごいち午後一gogoichi
1.

The earliest scheduled activity or event occurring in the afternoon of the same day.

2.

A colloquial reference to the exact time when the afternoon begins, typically denoting the very first task or appointment.